Department of Chemistry: Recent submissions
Now showing items 41-60 of 323
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Isolation and detailed 1H and 13C NMR structural assignment for three trachylobanes from Psiadia punctulata (Asteraceae) grown in Africa
(Elsevier, 2022-04-01)The first isolation of a trachylobane from an African specimen of Psiadia punctulata (Asteraceae) is presented in this paper. A complete 1H and 13C NMR spectral analysis of this compound and two other trachylobane diterpenes, ... -
A new gnidiflavanone-flavonol dimer and other constituents from Gnidia apiculata
(Taylor & Francis, 2022)A new 3,800-flavanone-flavonol dimer gnidiflavanone-flavonol (1) and 10 known compounds (2–11), including four rare primula type flavones 2–5, were isolated from the roots of Gnidia apicu lata. Compounds 2–5 and 7 were ... -
Synthesis of a pyrrolidine derivative of a carvotacetone and monoterpenes for anti-methicillin-resistant Staphylococcus aureus and anti-cryptococcal properties
(Taylor & Francis, 2022-05-03)Monoterpene derivatives are of great biological relevance in the pharmaceutical industry. In the present study, pyrrolidine deriva tive of a carvotacetone, 3-O-benzylcarvotacetone (1), and selected monoterpenes ... -
Assessment of Fluoride and selected heavy metals in food chain around Fluorspar mining Plant, Kenya
(GJEMPS, 2019)he purpose of the research was to assess the levels of fluoride and selected heavy metals in caprine, mutton, and vegetation around the Fluorspar mining plant in Kerio Valley. Previous studies have reported contamination ... -
A review of tobacco abuse and its epidemiological consequences
(Springer, 2021)Aim The economic burden caused by death and disease in the world is credited mainly to tobacco use—currently linked to approximately 8,000,000 deaths per year with approximately 80% of these faralities reported in low and ... -
Assessment of water quality of the Nyando River (Muhoroni-Kenya) using the water quality index (WQI) method
(Research gate, 2019)The quality of a river water is described by the levels of physico-chemical and microbiological parameters. The aim of the study was to determine the water quality of NyandoRiver water from four sampling stations (Muhoroni, ... -
Simultaneous quantification of acetaminophen and tryptophan using a composite graphene foam/Zr-MOF film modified electrode
(New Journal of Chemistry, 2020) -
Bioactive Analysis of Auricularia Delicata: Extraction, Purification, and Characterization of Polysaccharides from Auricularia Delicata-Morocco Forest
(Academia, 2020)Auricularia mushrooms are bioactive compounds which are mostly polysaccharides. Many studies have shown the use of Auricularia from wild mushroom for medicinal purposes such as antioxidant, antidiabetic, antitumor, ... -
Phytochemistry and insecticidal activity of Annona mucosa leaf extracts against Sitophilus zeamais and Prostephanus truncatus
(Taylor and Francis online, 2021)A new oleanane type triterpene characterized as 3α, 24-diacetoxy-12-oleanene (1) together with known compounds 2-10, were isolated from Annona mucosa leaf extracts. Their structural elucidation was accomplished using ... -
Effects of temperature and humidity and effectiveness of some selected antioxidants on lipid oreochromis niloticus L.) of Lake Victoria, Kenya
(Research Gate, 2021)Spoilage of fish and its related products due to oxidation is a primary problem leading to both loses in income and environmental degradation. Various methods such as sun-drying, smoking and refrigeration as currently ... -
Structural, Magnetic And Electronic Properties Of NbN Polymorphs By Ab-Initio Study
(2020)The structural, electronic and magnetic properties of NbN are studied by ab initio method by considering the four polymorphs {B1 (rock salt), B4 (wurtzite), B81 (NiAs) and Bh (WC-type)} of NbN. The results show that ... -
Covid-19 Evolution: Analysis of Public Health Countermeasures in Kenya.
(Research gate, 2020)Millions of people across the globe are currently at a risk of infection of SARS-Cov-2, have been infected and others have died. The coronavirus has spread worldwide despite the multiple countermeasures to limits its ... -
Synthesis, characterization and application of acid and alkaline activated volcanic ash-based geopolymers for adsorptive remotion of cationic and anionic dyes from water
(Elsevier, 2021)In this work, two geopolymers were prepared by acid activation (GPAc) and alkaline activation (GPAl) approaches using volcanic ash (VA) as the precursor material. The geosorbents were characterized by X-ray diffraction ... -
Single and binary adsorption of sulfonamide antibiotics onto iron‑modifed clay: linear and nonlinear isotherms, kinetics, thermodynamics, and mechanistic studies
(Springer, 2018)Iron-modifed raw kaolinite clay (Fe-MC) was synthesized by co-precipitation method, characterized, and then applied as a low-cost adsorbent to sequester sulfachloropyridazine (SCP) and sulfadimethoxine (SDM), emergent ... -
The effect of substituents on the reactivity of dichloridotriphenylphosphinoruthenium(II) complexes: kinetic and mechanistic study
(Taylor and Francis, 2021)The rates of substitution of chloro ligands from a series of ruthenium(II) complexes, [Ru(κ3-L)(PPh3)Cl2] (L = 2,2′:6′,2′′-terpyridine, 1; 4′-(4-methylphenyl)-2,2′:6′,2′′-terpyridine, 2; 4,4′4″-tri-tert-butyl-2,2′:6′,2′′ ... -
Synthesis and characterization of FSB@Fe3O4 composites and application in removal of indigo carmine dye from industrial wastewaters
(Springer, 2021)The syntheses and characterization of fish scale biochar magnetic composites (FSB@Fe3O4) and their applications in the removal of indigo carmine dye from effluents are described. Preparation of the fish scale biochar ... -
Controlling the reactivity of [Pd(II)(N^N^N)Cl]+ complexes using 2,6-bis(pyrazol-2-yl)pyridine ligands for biological application: Substitution reactivity, CT-DNA interactions and in vitro cytotoxicity study
(Elsevier, 2020)Four [(N^N^N)Pd(II)Cl]+ complexes [chloride-(2,2′:6′,2′′-terpyridine)Pd(II)]Cl (PdL1), [chlorido(2,6-bis(N-pyrazol-2-yl)pyridine)Pd(II)]Cl (PdL2), [chlorido(2,6-bis(3,5-dimethyl-N-pyrazol-2-yl)pyridine)Pd(II)]Cl (PdL3) and ... -
Toward a size scale-up cold sintering process at reduced uniaxial pressure
(The American Ceramic Society, 2019)Cold sintering is a low-temperature powder process methodology that enables the densification of ceramics and ceramic-based composites at significantly reduced times and temperatures. Although the general notion of ... -
Distribution and removal efficiency of heavy metals by a conventional activated sludge at a municipal wastewater treatment plant in Kisumu City
(International Science Community Association, 2017)The aim of this study was to evaluate the occurrence and the instantaneous overall efficiency of the municipal wastewater treatment facility in Kisumu City-Kenya, a highly populated City, and compare the effluent quality ...